How to pronounce“demjanov”in English
IPA/dɛmjænɒv/
Syllablesdem·ja·nov
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4:11
If the starting amine is a 1-aminomethyl-cycloalkanol – besides being a mouthful – it’s a potential reactant in the Tiffeneau-Demjanov rearrangement.
Named after Marc Tiffeneau and Nikolai Demjanov, the French and Russian chemists who worked on the mechanism, this rearrangement starts when this cyclic amino alcohol reacts with nitrous acid
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