How to pronounce“electron withdrawing”in English
So, putting these groups on the diene gets its HOMO closer to the energy of the dienophile’s LUMO.
Electron withdrawing groups on the dienophile lower the energy of its LUMO, which brings it even closer to the energy of the diene’s HOMO.
Let’s look at a specific example, with weakly electron donating methyl groups on our diene and electron withdrawing esters on our dienophile.
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